Synthesis of clausenin, xanthoxyletin, alloxanthoxyletin, xanthyletin and nor-dalbergin

Ganguly, A. K. ; Joshi, B. S. ; Kamat, V. N. ; Manmade, A. H. (1967) Synthesis of clausenin, xanthoxyletin, alloxanthoxyletin, xanthyletin and nor-dalbergin Tetrahedron, 23 (12). pp. 4777-4784. ISSN 0040-4020

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4020(01)92575-X

Abstract

The synthesis of clausenin is reported. Clausenin on methylation, NaBH4 reduction and dehydration of the secondary alcohol gives xanthoxyletin. The angular isomer of clausenin by a similar series of reactions gives alloxanthoxyletin. A convenient synthesis of xanthyletin and nor-dalbergin has also been achieved.

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