Sub-picosecond Raman spectroscopy and dynamics of nonequilibrium electrons and phonons in semiconductors

Abstract

Recent progress made in the use of time-resolved pump-probe Raman scattering technique to study the dynamics of photo-excited nonequilibrium carriers and LO-phonons in III-V semiconductors up to the sub-picosecond time scale will be discussed. It will be shown how this technique has allowed direct time-domain measurements of electron-LO-phonon scattering times for "hot" carriers and lifetimes for "hot" LO-phonons in semiconductors like GaAs. The presentation will include new experimental results of Kash, Jha and Tsang on picosecond Raman studies of the Frohlich interaction in alloys like Al _x Ga _1-x As and In _x Ga _1-x As. The present theoretical understanding of the dynamics of the highly excited carriers, dominated by strong LO-phonon emission, will be examined along with the discussion of a recent calculation of transient electrical conductivity of such hot carriers, showing extremely interesting oscillations with respect to the pump laser frequency, on the scale of the long wavelength LO-phonon frequency, and a highly nonlinear behaviour as a function of time.