Joseph, Jorly ; Ramachary, Dhevalapally B. ; Jemmis, Eluvathingal D. (2006) Electrostatic repulsion as an additional selectivity factor in asymmetric proline catalysis Organic & Biomolecular Chemistry, 4 . pp. 2685-2689. ISSN 1477-0520
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2006...
Related URL: http://dx.doi.org/10.1039/B606996G
Abstract
The metal free, single amino acid-catalyzed asymmetric desymmetrization (ADS) of meso-compounds 1 with nitrosobenzene 2 has been investigated using DFT. In this communication, we describe the role of electrostatic and dipole-dipole interactions in amino acid-catalyzed reactions, which has not previously been invoked in discussions of these important reactions.
| Item Type: | Article |
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| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 13624 |
| Deposited On: | 12 Nov 2010 15:32 |
| Last Modified: | 16 May 2016 22:46 |
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