Yadav, Jhillu S. ; Kavita, Aala ; Raghavendra Rao, Kovvuri V. ; Mohapatra, Debendra K. (2013) Studies directed towards the total synthesis of narbonolide: stereoselective synthesis of the C1–C15 chain Tetrahedron Letters, 54 (26). pp. 3329-3331. ISSN 0040-4039
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Official URL: http://doi.org/10.1016/J.Tetlet.2013.04.023
Related URL: http://dx.doi.org/10.1016/J.Tetlet.2013.04.023
Abstract
A stereoselective synthesis of the C1–C15 chain of narbonolide, a 14-membered macrolactone belonging to the pikromycin family of antibiotics is described. The key steps involved in this synthesis are desymmetrization of bicyclic olefin with Brown’s asymmetric hydroboration, Evans aldol reaction, Takai olefination and Yamaguchi esterification to yield the corresponding ester.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 135747 |
| Deposited On: | 14 Aug 2023 04:41 |
| Last Modified: | 14 Aug 2023 04:41 |
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