A Practical Total Synthesis of Both E- and Z-Isomers of Optically Pure (S)-14-Methylhexadec-8-enal (Trogodermal)

Yadav, Jhillu ; Chandravathi, Ch. ; Thrimurtulu, N. ; Prasad, A. ; Ghamdi, Ahmad (2013) A Practical Total Synthesis of Both E- and Z-Isomers of Optically Pure (S)-14-Methylhexadec-8-enal (Trogodermal) Synthesis, 45 (11). pp. 1513-1518. ISSN 0039-7881

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Official URL: http://doi.org/10.1055/S-0033-1338432

Related URL: http://dx.doi.org/10.1055/S-0033-1338432

Abstract

The total synthesis of both E- and Z-isomers of optically pure (S)-14-methylhexadec-8-enal (trogodermal) is described. Key steps involved Corey–Fuchs reaction, zipper isomerization, and different hydrogenation conditions for cis- and trans-isomers.

Item Type:Article
Source:Copyright of this article belongs to Georg Thieme Verlag KG.
ID Code:135739
Deposited On:11 Aug 2023 09:19
Last Modified:11 Aug 2023 09:19

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