Reddy, Gangireddy PavanKumar ; Reddy, J. Satyanarayana ; Das, Saibal ; Roisnel, Thierry ; Yadav, Jhillu S. ; Chandrasekhar, Srivari ; Grée, René (2013) Synthesis of Acylsilanes via Nickel-Catalyzed Reactions of α-Hydroxyallylsilanes Organic Letters, 15 (7). pp. 1524-1527. ISSN 1523-7060
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Official URL: http://doi.org/10.1021/Ol4003064
Related URL: http://dx.doi.org/10.1021/Ol4003064
Abstract
The redox isomerization processes and tandem isomerization-aldolization reactions, mediated by nickel catalysts, offer new versatile entries to acylsilanes. For the second reaction, high diastereoselectivities, up to 98:2, have been obtained with bulky substituents on silicon.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 135734 |
| Deposited On: | 11 Aug 2023 08:54 |
| Last Modified: | 11 Aug 2023 08:54 |
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