Raghavendra, S. ; Tadiparthi, Krishnaji ; Yadav, J.S. (2017) Total syntheses of Prelactone V and Prelactone B Carbohydrate Research, 442 . pp. 17-19. ISSN 0008-6215
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Official URL: http://doi.org/10.1016/J.Carres.2017.02.008
Related URL: http://dx.doi.org/10.1016/J.Carres.2017.02.008
Abstract
The total syntheses of natural products Prelactone-V and Prelactone-B have been accomplished by a novel Chiron approach starting from d-glucose. The synthesis involves isopropylidene acetal formation of d-glucose using Poly(4-vinylpyridine) supported iodine as a catalyst, Tebbe olefination, Grignard reaction, Wittig olefination, selective mono deprotection of acetal using PMA/SiO2, hydrogenation and anti-1,3-diol formation are as key steps.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 135688 |
| Deposited On: | 10 Aug 2023 07:57 |
| Last Modified: | 10 Aug 2023 07:57 |
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