Yadav, J.S. ; Swamy, T. ; Subba Reddy, B.V. ; Ravinder, V. (2014) Stereoselective synthesis of C19–C27 fragment of bryostatin 11 Tetrahedron Letters, 55 (30). pp. 4054-4056. ISSN 0040-4039
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Official URL: http://doi.org/10.1016/j.tetlet.2014.05.116
Related URL: http://dx.doi.org/10.1016/j.tetlet.2014.05.116
Abstract
A convergent synthesis of C19–C27 fragment (2) of bryostatin-11 is described. The key steps involved in this approach are kinetic resolution, Grignard reaction, and Sharpless dihydroxylation. AIBN catalyzed radical cyclization strategy has been used for the first time to construct the six-membered pyran system.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 135667 |
| Deposited On: | 17 Jul 2023 08:09 |
| Last Modified: | 17 Jul 2023 08:09 |
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