Stereoselective Total Synthesis of Rhoiptelol B via Prins Cyclization

Yadav, Jhillu ; Rahman, Md. ; Reddy, N. ; Prasad, Attaluri ; Al Khazim Al Ghamdi, Ahmad (2014) Stereoselective Total Synthesis of Rhoiptelol B via Prins Cyclization Synlett, 25 (05). pp. 661-664. ISSN 0936-5214

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Official URL: http://doi.org/10.1055/S-0033-1340181

Related URL: http://dx.doi.org/10.1055/S-0033-1340181

Abstract

The stereoselective total synthesis of rhoiptelol B, a diaryl­heptanoid isolated from Rhoiptelea chiliantha is described. The tetrahydropyran ring was constructed by using Prins cyclization. The key steps involved in this synthesis are Prins cyclization, Mistunobu inversion, cross metathesis, Sharpless asymmetric dihydroxylation, and hydrogenolysis.

Item Type:Article
Source:Copyright of this article belongs to Georg Thieme Verlag KG.
ID Code:135662
Deposited On:17 Jul 2023 08:01
Last Modified:17 Jul 2023 08:01

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