A unique self-assembly-driven probe for sensing a lipid bilayer: ratiometric probing of vesicle to micelle transition

Gulyani, Akash ; Dey, Nilanjan ; Bhattacharya, Santanu (2018) A unique self-assembly-driven probe for sensing a lipid bilayer: ratiometric probing of vesicle to micelle transition Chemical Communications, 54 (40). pp. 5122-5125. ISSN 1359-7345

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Official URL: http://doi.org/10.1039/c8cc01635f

Related URL: http://dx.doi.org/10.1039/c8cc01635f

Abstract

An amphiphilic pyrene–terpyridine (Pytpy) probe forms novel, fluorescent nanoaggregates in phospholipid membranes. This unique membrane-driven self-assembly of Pytpy shows large Stokes shifts and long-lived fluorescent states and efficiently reports on vesicle–micelle transition through ratiometric changes. Strikingly, Pytpy can even distinguish between bilayer-like domains and more-dynamic micelle-like ‘rim’ phases that co-exist in mixed assemblies (bicelles).

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:134229
Deposited On:05 Jan 2023 10:55
Last Modified:05 Jan 2023 10:55

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