Role of synergistic π–π stacking and X–H⋯Cl (X = C, N, O) H-bonding interactions in gelation and gel phase crystallization

Bhattacharjee, Subham ; Bhattacharya, Santanu (2015) Role of synergistic π–π stacking and X–H⋯Cl (X = C, N, O) H-bonding interactions in gelation and gel phase crystallization Chemical Communications, 51 (32). pp. 7019-7022. ISSN 1359-7345

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Official URL: http://doi.org/10.1039/c5cc00930h

Related URL: http://dx.doi.org/10.1039/c5cc00930h

Abstract

The self-assembly of p-pyridyl-ended oligo-p-phenylenevinylenes (OPVs) in ethanol leads to the formation of either hollow or solid microrods. The corresponding protonated OPVs with n-butyl chains induce transparent gelation and also gel phase crystallization owing to various synergistic noncovalent interactions. The chloride ion-selective gelation, AIEE and stimuli responsiveness of the gel are also observed.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:134136
Deposited On:05 Jan 2023 07:56
Last Modified:05 Jan 2023 07:56

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