Formation of organorhodium complexes via C–H bond activation of 1,3-di(phenylazo)benzene

Majumder, Paramita ; Baksi, Suparna ; Halder, Sarmistha ; Tadesse, Haregewine ; Blake, Alexander J. ; Drew, Michael G. B. ; Bhattacharya, Samaresh (2011) Formation of organorhodium complexes via C–H bond activation of 1,3-di(phenylazo)benzene Dalton Transactions, 40 (20). p. 5423. ISSN 1477-9226

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Official URL: http://doi.org/10.1039/C1DT10247H

Related URL: http://dx.doi.org/10.1039/C1DT10247H

Abstract

Reaction of a potential NCN-pincer ligand, viz. 1,3-di(phenylazo)benzene (L), with [Rh(PPh3)3Cl] affords, via a C–H bond activation, an interesting dinuclear Rh(II) complex (1), and with RhCl3·3H2O affords a mononuclear Rh(III) complex (2) containing a catalytically useful Rh-OH2 fragment.

Item Type:Article
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Deposited On:03 Jan 2023 09:33
Last Modified:03 Jan 2023 09:33

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