Talukdar, Dhrubajyoti ; Borah, Suchibrata ; Chaudhuri, Mihir K. (2015) Bis(acetylacetonato)copper(II) catalyzed oxidative cross-dehydrogenative coupling (CDC) for the synthesis of α-acyloxy ethers through direct activation of α-C(sp3)–H bond of cyclic ether Tetrahedron Letters, 56 (20). pp. 2555-2558. ISSN 00404039
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Official URL: http://doi.org/10.1016/j.tetlet.2015.03.068
Related URL: http://dx.doi.org/10.1016/j.tetlet.2015.03.068
Abstract
A bis(acetylacetonato)copper(II)catalyzed convenient protocol has been developed for the synthesis of α-acyloxy ethers via cross-dehydrogenative coupling (CDC) using tertiary-butylhydroperoxide (TBHP) as the oxidant. A radical mechanism is suggested for the reaction.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Ltd |
| Keywords: | Bis(acetylacetonato)copper(II)α-Acyloxy ethers;Cross-dehydrogenative coupling;Tertiary-butylhydroperoxide (TBHP)C–O bond formation |
| ID Code: | 134042 |
| Deposited On: | 03 Jan 2023 08:46 |
| Last Modified: | 03 Jan 2023 08:46 |
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