Mukherjee, Aparajita ; Hrovat, David A. ; Richmond, Michael G. ; Bhattacharya, Samaresh (2018) A new diphosphine-carbonyl complex of ruthenium: an efficient precursor for C–C and C–N bond coupling catalysis Dalton Transactions, 47 (30). pp. 10264-10272. ISSN 1477-9226
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Official URL: http://doi.org/10.1039/C8DT01085D
Related URL: http://dx.doi.org/10.1039/C8DT01085D
Abstract
Reaction of 1,2-bis(diphenylphosphino)benzene (dppbz) with [{Ru(CO)2Cl2}n] affords [Ru(dppbz)(CO)2Cl2], where the two carbonyls are mutually cis and the two chlorides are trans. The molecular structure of [Ru(dppbz)(CO)2Cl2], has been determined by X-ray crystallography, and the stability of the different available stereoisomers has been computationally evaluated. [Ru(dppbz)(CO)2Cl2] has been found to serve as an excellent pre-catalyst for catalytic Suzuki-type C–C coupling and Buchwald-type C–N coupling reactions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 134016 |
| Deposited On: | 03 Jan 2023 06:03 |
| Last Modified: | 03 Jan 2023 06:03 |
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