Palladium nanoparticles catalyzed aroylation of NH-sulfoximines with aryl iodides

Sharma, Nidhi ; Sekar, Govindasamy (2016) Palladium nanoparticles catalyzed aroylation of NH-sulfoximines with aryl iodides RSC Advances, 6 (43). pp. 37226-37235. ISSN 2046-2069

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Official URL: http://doi.org/10.1039/c6ra05334c

Related URL: http://dx.doi.org/10.1039/c6ra05334c

Abstract

A novel approach towards aroylation of NH-sulfoximines using Pd nanoparticles stabilized by a binaphthyl backbone (Pd-BNP) has been developed. This synthetic protocol involves the Pd-BNP promoted carbon monoxide insertion of aryl iodides to form an aroyl intermediate which further reacts with NH-sulfoximines to form N-aroyl sulfoximine derivatives in good to excellent yields. The Pd-BNP catalyst was recovered and reused up to six times.

Item Type:Article
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ID Code:132604
Deposited On:20 Dec 2022 07:54
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