High-pressure Raman study of K and T forms of the octachloro cyclic phosphazene tetramer P4 N4 CI8

Victor, D. ; Muthu, S. ; Chandrabhas, N. ; Sood, A. K. ; Venkatesan, K. ; Venugopalan, P. ; Jayaraman, A. (1992) High-pressure Raman study of K and T forms of the octachloro cyclic phosphazene tetramer P4 N4 CI8 Journal of Raman Spectroscopy, 23 (11). pp. 611-614. ISSN 0377-0486

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/jrs.125...

Related URL: http://dx.doi.org/10.1002/jrs.1250231106

Abstract

The octachloro cyclic phosphazene tetramer P4N4Cl8 was studied by high-pressure Raman spectroscopy up to 10 GPa in the K form (boat-shaped molecule) and in the T form (chair-shaped molecule). There are pressure-induced phase transitions in the crystal with the K-form molecules. There is a conformation change from the T to the K form under a non-hydrostatic pressure of less than 0.7 GPa.

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Deposited On:11 Nov 2010 07:02
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