N-Methylpyrrolidone Hydroperoxide/Cs2CO3as an Excellent Reagent System for the Hydroxy-Directed Diastereoselective Epoxidation of Electron-Deficient Olefins

Victor, Napoleon John ; Gana, Janardhanan ; Muraleedharan, Kannoth Manheri (2015) N-Methylpyrrolidone Hydroperoxide/Cs2CO3as an Excellent Reagent System for the Hydroxy-Directed Diastereoselective Epoxidation of Electron-Deficient Olefins Chemistry - A European Journal, 21 (42). pp. 14742-14747. ISSN 0947-6539

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Official URL: http://doi.org/10.1002/chem.201501929

Related URL: http://dx.doi.org/10.1002/chem.201501929

Abstract

Something kinda HOO-: This report introduces N-methylpyrrolidone hydroperoxide/base as an excellent system for the hydroxy-directed syn-selective epoxidation of electron-deficient olefins, characterized by high diastereoselectivity, short reaction times and remarkable chemoselectivity, especially in the presence of oxidatively labile nitrogen or sulfur atoms.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons, Inc.
ID Code:131832
Deposited On:08 Dec 2022 11:54
Last Modified:08 Dec 2022 11:54

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