Yadagiri, Dongari ; Anbarasan, Pazhamalai (2015) An iodine(iii) mediated oxidative rearrangement of enamines: efficient synthesis of α-amino ketones Chemical Communications, 51 (75). pp. 14203-14206. ISSN 1359-7345
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Official URL: http://doi.org/10.1039/c5cc04265h
Related URL: http://dx.doi.org/10.1039/c5cc04265h
Abstract
An iodine(III)-mediated, group-selective oxidative rearrangement of β,β-diarylenamines to α-amino ketones has been accomplished with excellent yield. The developed reaction involves the initial oxidation of enamine to an α-acyloxyimine intermediate and concomitant semipinacol rearrangement.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 131807 |
| Deposited On: | 08 Dec 2022 09:58 |
| Last Modified: | 08 Dec 2022 09:58 |
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