Yadagiri, Dongari ; Anbarasan, Pazhamalai (2014) Rhodium Catalyzed Direct Arylation of α-Diazoimines Organic Letters, 16 (9). pp. 2510-2513. ISSN 1523-7060
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Official URL: http://doi.org/10.1021/ol500874p
Related URL: http://dx.doi.org/10.1021/ol500874p
Abstract
An efficient rhodium catalyzed direct arylation of α-diazoimines, generated from readily accessible 1,2,3-triazole, has been accomplished for the synthesis of 2,2-diaryl enamides. The reaction involves the chemo- and regioselective insertion of rhodium azavinyl carbene into aromatic C(sp(2))-H bonds. Utility of the developed methodology was demonstrated in the synthesis of indole and tetrahydroisoquinoline frameworks.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 131585 |
| Deposited On: | 07 Dec 2022 07:52 |
| Last Modified: | 07 Dec 2022 07:52 |
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