Palladium Catalyzed Aryl(alkyl)thiolation of Unactivated Arenes

Saravanan, Perumal ; Anbarasan, Pazhamalai (2014) Palladium Catalyzed Aryl(alkyl)thiolation of Unactivated Arenes Organic Letters, 16 (3). pp. 848-851. ISSN 1523-7060

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Official URL: http://doi.org/10.1021/ol4036209

Related URL: http://dx.doi.org/10.1021/ol4036209

Abstract

A general palladium-catalyzed aryl(alkyl)thiolation of various substituted unactivated arenes is accomplished for the synthesis of diverse unsymmetrical diaryl(alkyl) sulfides in good yield employing electrophilic sulfur reagent 6 derived from succinimide. The developed strategy was coupled with intramolecular arylation of a C-H bond to afford dibenzothiphene derivatives, an important moiety in material science as organic semiconductors.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:131581
Deposited On:07 Dec 2022 07:44
Last Modified:07 Dec 2022 07:44

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