Reductive lithiation of bis-phenylsulfones

Yu, Jurong ; Cho, Hyun-Sung ; Chandrasekhar, S. ; Falck, J.R. ; Mioskowski, Charles (1994) Reductive lithiation of bis-phenylsulfones Tetrahedron Letters, 35 (30). pp. 5437-5440. ISSN 00404039

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Official URL: http://doi.org/10.1016/S0040-4039(00)73519-2

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)73519-2

Abstract

Reductive cleavage of geminal bis-phenylsulfones using lithium naphthalenide in THF at −78°C selectively affords α-sulfonyl carbanions which participate in typical reaction with electrophiles. Reductive cleavage of geminal bis-phenylsulfones using lithium naphthalenide in THF at −78°C selectively affords α-sulfonyl carbanions which participate in typical reactions with electrophiles.

Item Type:Article
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