Caveat in alkylative fragmentation of aldehyde tosylhydrazones of cyclic ethers

Chandrasekhar, S. ; Venkat Reddy, M. ; Takhi, Mohamed (1998) Caveat in alkylative fragmentation of aldehyde tosylhydrazones of cyclic ethers Tetrahedron Letters, 39 (36). pp. 6535-6538. ISSN 00404039

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Official URL: http://doi.org/10.1016/S0040-4039(98)01359-8

Related URL: http://dx.doi.org/10.1016/S0040-4039(98)01359-8

Abstract

Tosylhtdrazones of aldehydes at the α-position of cyclic ethers when exposed to carbon nucleophiles produce either ring opened alkylated olefinic alcohols and/or cyclic alkylated vinyl ethers, the ratio of which is dependent on nature of hydrazone and nucleophile used.

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