Synthesis and Self-Assembly of Bolaamphiphiles Based onβ-Amino Acids or an Alcohol

Mainkar, Prathama S. ; Sridhar, Chirumarry ; Sudhakar, Ambadi ; Chandrasekhar, Srivari (2013) Synthesis and Self-Assembly of Bolaamphiphiles Based onβ-Amino Acids or an Alcohol Helvetica Chimica Acta, 96 (1). pp. 99-108. ISSN 0018019X

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Official URL: http://doi.org/10.1002/hlca.201200060

Related URL: http://dx.doi.org/10.1002/hlca.201200060

Abstract

The synthesis of bolaamphiphiles from unusual β-amino acids or an alcohol and C12 or C20 spacers is described. Unusual β-amino acids such as a sugar amino acid, an AZT-derived amino acid, a norbornene amino acid, and an AZT-derived amino alcohol were coupled with spacers under standard conditions to get the novel bolaamphiphiles 5–8 (Scheme 1), 12 and 13 (Scheme 2), and 17 and 20 (Scheme 3). Some of these compounds, on precipitation from MeOH/H2O, self-assembled into organized molecular structures.

Item Type:Article
Source:Copyright of this article belongs to John Wiley & Sons, Inc
ID Code:131347
Deposited On:06 Dec 2022 10:53
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