Chandrasekhar, Srivari ; Gaddam, Vikram ; Nadella, Lavanya ; Sukumar, Genji ; Mainkar, Prathama (2018) Stereoselective Synthesis of Northern Fragment of Eribulin Mesylate from d-Mannose Synthesis, 50 (09). pp. 1901-1906. ISSN 0039-7881
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Official URL: http://doi.org/10.1055/s-0036-1591769
Related URL: http://dx.doi.org/10.1055/s-0036-1591769
Abstract
Stereoselective synthesis of northern fragment of eribulin mesylate is reported by coupling of the C1–C13 fragment with the C28–C35 fragment. The key steps involved in this synthesis are butyllithium-facilitated coupling between sulfone and aldehyde, then Dess–Martin periodinane oxidation followed by samarium(II) iodide mediated desulfonylation.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Georg Thieme Verlag KG |
| ID Code: | 131296 |
| Deposited On: | 06 Dec 2022 09:18 |
| Last Modified: | 06 Dec 2022 09:18 |
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