Sonti, Rajesh ; Gowd, Konkallu Hanumae ; Rao, K. N. Shashanka ; Ragothama, Srinivasarao ; Rodriguez, Alex ; Perez, Juan Jesus ; Balaram, Padmanabhan (2013) Conformational Diversity in Contryphans fromConusVenom:cis-transIsomerisation and Aromatic/Proline Interactions in the 23-Membered Ring of a 7-Residue Peptide Disulfide Loop Chemistry - A European Journal, 19 (45). pp. 15175-15189. ISSN 0947-6539
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Official URL: http://doi.org/10.1002/Chem.201301722
Related URL: http://dx.doi.org/10.1002/Chem.201301722
Abstract
Flexibility in rigid structures: The ability of nature to synthesize constrained disulfide-bonded cyclic molecules which adopt well-defined multiple conformational states is highlighted. Aromatic/proline interactions modulate cis–trans equilibria about Xxx–Pro bonds in the 23-membered heterocyclic ring of the contryphans isolated from cone snail venom.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| ID Code: | 131240 |
| Deposited On: | 06 Dec 2022 05:27 |
| Last Modified: | 06 Dec 2022 05:27 |
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