Rhodium-Catalyzed Transannulation of 1,2,3-Triazoles to Polysubstituted Pyrroles

Rajasekar, Shanmugam ; Anbarasan, Pazhamalai (2014) Rhodium-Catalyzed Transannulation of 1,2,3-Triazoles to Polysubstituted Pyrroles Journal of Organic Chemistry, 79 (17). pp. 8428-8434. ISSN 0022-3263

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Official URL: http://doi.org/10.1021/jo501043h

Related URL: http://dx.doi.org/10.1021/jo501043h

Abstract

Rhodium-catalyzed transannulation of N-sulfonyl-1,2,3-triazoles with vinyl ether has been accomplished for the synthesis of various polysubstituted pyrroles. The present method allows the synthesis of mono-, di-, and trisubstituted pyrroles with appropriate substitutions. Furthermore, the developed methodology was applied in the formal synthesis of neolamellarin A, an antitumor agent.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:131140
Deposited On:02 Dec 2022 11:36
Last Modified:02 Dec 2022 11:36

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