One-pot synthesis of self-assembled heteroleptic palladium(II) complexes with tmeda: An application of ligand exchange reactions

Bandi, Sreenivasulu ; Debata, Niladri Bihari ; Ramkumar, Venkatachalam ; Chand, Dillip Kumar (2014) One-pot synthesis of self-assembled heteroleptic palladium(II) complexes with tmeda: An application of ligand exchange reactions Inorganic Chemistry Communications, 39 . pp. 75-78. ISSN 1387-7003

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Official URL: http://doi.org/10.1016/j.inoche.2013.10.047

Related URL: http://dx.doi.org/10.1016/j.inoche.2013.10.047

Abstract

One-pot synthesis of self-assembled heteroleptic complexes of general formula [Pdx(tmeda)x(L)y](NO3)2x is achieved by combining required amount of tmeda, a chosen ligand L and Pd(NO3)2 under suitable reaction conditions. The strategy is devised using our understanding of a special variety of ligand exchange reactions (LER) around palladium(II) centers as modeled in this work. The one-pot synthesis technique is thus considered as an application of the unique LER.

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