Halder, Prasenjit ; Krishnan, Mangala Sunder ; Arunan, E. (2020) Coriolis Interactions in benzene-water and related molecular complexes Journal of Molecular Spectroscopy, 370 . p. 111277. ISSN 00222852
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Official URL: http://doi.org/10.1016/j.jms.2020.111277
Related URL: http://dx.doi.org/10.1016/j.jms.2020.111277
Abstract
Rotational spectra of benzene-water and several related complexes were fit according to a free internal rotor model over the last three decades, though the model did not explain all of the excited state transitions found or yield an RMS deviation within experimental uncertainty. We use a model Hamiltonian, including Coriolis interactions that is able to explain all excited state transitions observed, giving a fit with an RMS deviation within experimental uncertainty.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Inc. |
| Keywords: | Molecular complex, l-type doubling, Microwave spectroscopy, van der Waals complex, Coriolis coupling, Hydrogen bonding |
| ID Code: | 131011 |
| Deposited On: | 02 Dec 2022 06:15 |
| Last Modified: | 02 Dec 2022 06:15 |
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