Kotha, Surya Srinivas ; Chandrasekar, Selvaraj ; Sahu, Samrat ; Sekar, Govindasamy (2014) Iron-TEMPO-Catalyzed Domino Aerobic Alcohol Oxidation/Oxidative Cross-Dehydrogenative Coupling for the Synthesis of α-Keto Amides European Journal of Organic Chemistry, 2014 (33). pp. 7451-7457. ISSN 1434-193X
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Official URL: http://doi.org/10.1002/ejoc.201402961
Related URL: http://dx.doi.org/10.1002/ejoc.201402961
Abstract
An iron-TEMPO-catalyzed (TEMPO = 2,2,6,6-tetramethyl-1-piperidinyloxy), aerobic process was developed to synthesize α-keto amides. This reaction proceeds through a domino alcohol oxidation/oxidative cross-dehydrogenative coupling sequence, uses 2-hydroxyacetophenones and amines as the starting materials, and takes place under molecular oxygen, which makes the transformation highly efficient, practical, and environmentally friendly.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| ID Code: | 130983 |
| Deposited On: | 02 Dec 2022 05:07 |
| Last Modified: | 02 Dec 2022 05:07 |
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