Pati, Anita ; Athilakshmi, Jeyaraman ; Ramkumar, Venkatachalam ; Chand, Dillip Kumar (2014) A two-dimensional polydodecameric water–chloride cluster enfolding (Hg–Cl–Hg)+concealed cascade cryptate CrystEngComm, 16 (30). p. 6827. ISSN 1466-8033
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Official URL: http://doi.org/10.1039/c4ce00802b
Related URL: http://dx.doi.org/10.1039/c4ce00802b
Abstract
An intriguing phenomenon of a hitherto unknown type of cavity induced “reductive encapsulation” using Hg(II) and a homoditopic octaaza cryptand is described. The crystal structure of the complex offers a new type of grid-like polydodecameric water–chloride cluster, {[(H2O)12(Cl)]1−}n, that renders the highest number of water molecules per chloride reported thus far.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 130720 |
| Deposited On: | 29 Nov 2022 09:20 |
| Last Modified: | 29 Nov 2022 09:20 |
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