Anju, R. S. ; Roy, Dipak Kumar ; Mondal, Bijan ; Yuvaraj, K. ; Arivazhagan, C. ; Saha, Koushik ; Varghese, Babu ; Ghosh, Sundargopal (2014) Reactivity of Diruthenium and Dirhodium Analogues of Pentaborane(9): Agostic versus Boratrane Complexes Angewandte Chemie International Edition, 53 (11). pp. 2873-2877. ISSN 1433-7851
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Official URL: http://doi.org/10.1002/anie.201310416
Related URL: http://dx.doi.org/10.1002/anie.201310416
Abstract
All in a bind of a different kind: Boron–transition-metal complexes with novel binding modes were synthesized efficiently from diruthenium and dirhodium analogues of pentaborane(9) without the use of preformed boron-containing ligands. The observed binding modes included an agostic interaction, a metalladiborane structure, and a boratrane (see structures I–III). A thioborane with a tantalum center (structure IV) is also described.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| ID Code: | 130652 |
| Deposited On: | 29 Nov 2022 05:11 |
| Last Modified: | 29 Nov 2022 05:11 |
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