Studies on iodination reactions of phosphiniminocyclotrithiazenes

Sivaramakrishna, Akella ; Swarnalatha, U. ; Sudheendra Rao, M. N. (2013) Studies on iodination reactions of phosphiniminocyclotrithiazenes Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 43 (10). pp. 1349-1354. ISSN 1553-3174

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Official URL: http://doi.org/10.1080/15533174.2012.759231

Related URL: http://dx.doi.org/10.1080/15533174.2012.759231

Abstract

Iodination reactions of various phosphiniminocyclotrithiazenes [R3PNS3N3; R = (i) phenyl-, (ii) morpholino-, and (iii) p-chlorophenyl-] have been studied under different experimental conditions. Iodination of Ph3PNS3N3 yields interesting products such as [(Ph3PN)2S3N3]I3, ((Ph3PN)3S)2I4, (Ph3PNH2)I3, ((Ph3PSI2)2I2, and [(Ph3PN)3SO]2I6 depending on the experimental conditions. All the products have been isolated and characterized by the spectroscopic and analytical techniques.

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