Chaitanya, Manthena ; Yadagiri, Dongari ; Anbarasan, Pazhamalai (2013) Rhodium Catalyzed Cyanation of Chelation Assisted C–H Bonds Organic Letters, 15 (19). pp. 4960-4963. ISSN 1523-7060
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Official URL: http://doi.org/10.1021/ol402201c
Related URL: http://dx.doi.org/10.1021/ol402201c
Abstract
A rhodium-catalyzed cyanation of chelation assisted C-H bonds is described employing N-cyano-N-phenyl-p-methylbenzenesulfonamide as an efficient cyanating reagent. The present method allowed the synthesis of various benzonitirle derivatives in good to excellent yield. A number of chelating groups are also effective in the present cyanation of C-H bonds. In addition, the developed methodology was applied in the formal synthesis of the isoquinoline alkaloid, menisporphine.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 130456 |
| Deposited On: | 25 Nov 2022 07:25 |
| Last Modified: | 25 Nov 2022 07:25 |
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