Saravanakumar, Rajendran ; Ramkumar, Venkatachalam ; Sankararaman, Sethuraman (2013) Synthesis and structural characterization of cis isomer of 1,2,3-triazol-5-ylidene based palladium complexes Journal of Organometallic Chemistry, 736 . pp. 36-41. ISSN 0022-328X
Full text not available from this repository.
Official URL: http://doi.org/10.1016/j.jorganchem.2013.03.008
Related URL: http://dx.doi.org/10.1016/j.jorganchem.2013.03.008
Abstract
Mild thermolysis of arachno-[(Cp*RuCO)2B2H6], 1 in presence of GeCl2·dioxane yielded di-μ-germylene complex [(Cp*Ru)2(μ-GeCl2)2(CO)2], 2 (Cp* = η5-C5Me5). The molecular structure of 2 exhibits a diruthenium unit bridged by a pair of μ-GeCl2 moieties. The Cp* and the terminal CO ligands are oriented in anti fashion with respect to Ru–Ru bond. In addition, the reaction of 2 with arachno-[CpFe(CO)B3H8] (Cp = η5-C5H5) transformed to germenocene, [Cp2Ge:], 3 via an unstable intermediate [CpFe(CO)B2H5GeCl2], I. The 11B NMR spectroscopy was used as a tool to establish a probable reaction pathway for the formation of germenocene 3. Cluster 2 has been characterized by IR and NMR spectroscopy, and the geometric structure was unequivocally established by crystallographic analysis.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 130357 |
| Deposited On: | 24 Nov 2022 10:52 |
| Last Modified: | 24 Nov 2022 10:52 |
Repository Staff Only: item control page
