Novel Triple-Decker Sandwich Complex with a Six-Membered [B3Co2(μ4-Te)] Ring as the Middle Deck

Thakur, Arunabha ; Chakrahari, Kiran Kumar Varma ; Mondal, Bijan ; Ghosh, Sundargopal (2013) Novel Triple-Decker Sandwich Complex with a Six-Membered [B3Co2(μ4-Te)] Ring as the Middle Deck Inorganic Chemistry, 52 (5). pp. 2262-2264. ISSN 0020-1669

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Official URL: http://doi.org/10.1021/ic3022358

Related URL: http://dx.doi.org/10.1021/ic3022358

Abstract

Thermolysis of nido-[(Cp*Mo)2B4TeClH5], with an excess of Co2(CO)8 at room temperature, afforded a triple-decker sandwich complex [(Cp*Mo)2{μ-η(6):η(6)-B3H3TeCo2(CO)5}] (4), which represents an unsaturated 24-valence-electron sandwich cluster in which the middle deck is composed of B, Co, and a heavy group 16 element.

Item Type:Article
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ID Code:130319
Deposited On:24 Nov 2022 06:49
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