Gharpure, Santosh J. ; Reddy, S. Raja Bhushan (2013) Stereoselective Synthesis of Benzoxepines through Tandem Alkylation/Michael Addition to Vinylogous Carbonates European Journal of Organic Chemistry, 2013 (15). pp. 2981-2984. ISSN 1434-193X
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Official URL: http://doi.org/10.1002/ejoc.201300267
Related URL: http://dx.doi.org/10.1002/ejoc.201300267
Abstract
A tandem SN2 alkylation/Michael addition to vinylogous carbonates based approach for the stereoselective synthesis of benzoxepines is developed. The stereoselectivity improves with an increase in the steric bulk of the substituents. The method is extended to the synthesis of benzopyranoxepines and benzoxepinopyridines with angular substituents.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| ID Code: | 130303 |
| Deposited On: | 02 Dec 2022 05:54 |
| Last Modified: | 05 Dec 2022 06:09 |
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