Anju, R. S. ; Roy, Dipak Kumar ; Geetharani, K. ; Mondal, Bijan ; Varghese, Babu ; Ghosh, Sundargopal (2013) A fine tuning of metallaborane to bridged-boryl complex, [(Cp*Ru)2(μ-H)(μ-CO)(μ-Bcat)] (cat = 1,2-O2C6H4; Cp* = η5-C5Me5) Dalton Transactions, 42 (36). p. 12828. ISSN 1477-9226
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Official URL: http://doi.org/10.1039/c3dt51138c
Related URL: http://dx.doi.org/10.1039/c3dt51138c
Abstract
Room temperature photolysis of [(Cp*RuCO)2BH4(Bcat)], 3, generated from the reaction of arachno-[(Cp*RuCO)2B2H6], 1, with HBcat (cat = 1,2-O2C6H4), yielded a rare homodinuclear bridged-boryl complex, [(Cp*Ru)2(μ-H)(μ-CO)(μ-Bcat)], 4, confirmed by X-ray diffraction.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 130294 |
| Deposited On: | 02 Dec 2022 05:54 |
| Last Modified: | 05 Dec 2022 06:09 |
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