2,4,6,8-Tetrakis(2-fluorophenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one

Park, Dong Ho ; Ramkumar, V. ; Parthiban, P. (2013) 2,4,6,8-Tetrakis(2-fluorophenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one Acta Crystallographica Section E, 69 (2). o179-o179. ISSN 1600-5368

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Official URL: http://doi.org/10.1107/S1600536812051574

Related URL: http://dx.doi.org/10.1107/S1600536812051574

Abstract

The title compound, C(31)H(24)F(4)N(2)O, exists in a chair-boat conformation with an equatorial orientation of the 2-fluoro-phenyl groups on both sides of the secondary amino group of the chair form. The benzene rings in the 'chair' part are inclined to each other at 19.4 (1)°, while the equivalent angle between the benzene rings in the 'boat' part is 75.6 (1)°. One F atom was treated as disordered over two positions in a 0.838 (4):0.162 (4) ratio. In the crystal, N-H⋯O hydrogen bonds link the mol-ecules into chains along [001] and these chains are held together via weak N-H⋯F and C-H⋯F inter-actions.

Item Type:Article
Source:Copyright of this article belongs to International Union of Crystallography.
ID Code:130205
Deposited On:23 Nov 2022 08:59
Last Modified:23 Nov 2022 08:59

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