Baylis-Hillman Bromides as a Source of 1,3-Dipoles: Sterically Directed Synthesis of Oxindole-Fused Spirooxirane and Spirodihydrofuran Frameworks

Basavaiah, Deevi ; Badsara, Satpal Singh ; Sahu, Bharat Chandra (2013) Baylis-Hillman Bromides as a Source of 1,3-Dipoles: Sterically Directed Synthesis of Oxindole-Fused Spirooxirane and Spirodihydrofuran Frameworks Chemistry - A European Journal, 19 (9). pp. 2961-2965. ISSN 0947-6539

Full text not available from this repository.

Official URL: http://doi.org/10.1002/chem.201203756

Related URL: http://dx.doi.org/10.1002/chem.201203756

Abstract

The sterically directed [3+2] cycloaddition reactions of dipoles that were generated from Baylis–Hillman bromides with isatin dipolarophiles provided a facile synthetic route to spirodihydrofuran oxindoles and spiroepoxy oxindoles (see scheme). a)–c) Me2S, Cs2CO3, DMF, 15–20 °C, N2, 8 h. EWG: a) CO2Me (Z), b) CO2Me, and c) CN (E).

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons, Inc.
ID Code:130105
Deposited On:05 Dec 2022 05:54
Last Modified:05 Dec 2022 05:54

Repository Staff Only: item control page