Synthesis of Angularly Fused Aromatic Compounds from Alkenyl Enediynes by a Tandem Radical Cyclization Process

Roy, Snigdha ; Anoop, Anakuthil ; Biradha, Kumar ; Basak, Amit (2011) Synthesis of Angularly Fused Aromatic Compounds from Alkenyl Enediynes by a Tandem Radical Cyclization Process Angewandte Chemie International Edition, 50 (36). pp. 8316-8319. ISSN 1433-7851

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Official URL: http://doi.org/10.1002/Anie.201103318

Related URL: http://dx.doi.org/10.1002/Anie.201103318

Abstract

Let's get radical: A general synthetic route toward angularly ortho-fused polyaromatic [4]helicenes starting from aryl alkenyl N-substituted cyclic enediynes is described (see scheme; DMSO=dimethyl sulfoxide, Ns=4-nitrobenzenesulfonyl). The process involved a Bergman cyclization (BC) as the key step of an unprecedented tandem radical reaction.

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ID Code:129880
Deposited On:21 Nov 2022 10:28
Last Modified:21 Nov 2022 10:28

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