Reaction of Diaryl-1,2-diones with Triphenylphosphine and Diethyl Azodicarboxylate Leading to N,N-Dicarboethoxy Monohydrazones via a Novel Rearrangement

Nair, Vijay ; Biju, A. T. ; Abhilash, K. G. ; Menon, Rajeev S. ; Suresh, Eringathodi (2005) Reaction of Diaryl-1,2-diones with Triphenylphosphine and Diethyl Azodicarboxylate Leading to N,N-Dicarboethoxy Monohydrazones via a Novel Rearrangement Organic Letters, 7 (11). pp. 2121-2123. ISSN 1523-7060

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Official URL: http://doi.org/10.1021/ol050403+

Related URL: http://dx.doi.org/10.1021/ol050403+

Abstract

A mechanistically novel reaction of diaryl-1,2-diones with diethyl azodicarboxylate and triphenylphosphine to afford N,N-dicarboethoxy monohydrazones is described. The reaction proceeds via a nitrogen to nitrogen migration of a carboethoxy group.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society
ID Code:128756
Deposited On:03 Nov 2022 06:58
Last Modified:11 Nov 2022 04:07

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