Biju, Akkattu T. ; Glorius, Frank (2010) Intermolecular N-Heterocyclic Carbene Catalyzed Hydroacylation of Arynes Angewandte Chemie International Edition, 49 (50). pp. 9761-9764. ISSN 14337851
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Official URL: http://doi.org/10.1002/anie.201005490
Related URL: http://dx.doi.org/10.1002/anie.201005490
Abstract
A formal introduction: The conceptually new N-heterocyclic carbene catalyzed formal insertion of arynes into the CformylH bond of aldehydes demonstrates the compatibility of nucleophilic NHCs with electrophilic arynes. This NHC-catalyzed hydroacylation of arynes allows the conversion of aliphatic, α,β-unsaturated, and aromatic aldehydes into aryl ketones; 27 examples and a preliminary mechanistic investigation are provided.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| ID Code: | 128731 |
| Deposited On: | 03 Nov 2022 06:56 |
| Last Modified: | 03 Nov 2022 06:56 |
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