Bhunia, Anup ; Yetra, Santhivardhana Reddy ; Bhojgude, Sachin Suresh ; Biju, Akkattu T. (2012) Efficient Synthesis of γ-Keto Sulfones by NHC-Catalyzed Intermolecular Stetter Reaction Organic Letters, 14 (11). pp. 2830-2833. ISSN 1523-7060
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Official URL: http://doi.org/10.1021/ol301045x
Related URL: http://dx.doi.org/10.1021/ol301045x
Abstract
The N-heterocyclic carbene-catalyzed intermolecular Stetter reaction of aldehydes with α,β-unsaturated sulfones allows the atom-economic and selective formation of γ-keto sulfones in good yields. Key to the success of this unique transition-metal-free carbon-carbon bond-forming reaction is the right choice of the NHC precursor and base. The reaction tolerates a broad range of different aldehydes.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society |
| ID Code: | 128707 |
| Deposited On: | 03 Nov 2022 06:54 |
| Last Modified: | 03 Nov 2022 06:54 |
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