Bhojgude, Sachin Suresh ; Kaicharla, Trinadh ; Bhunia, Anup ; Biju, Akkattu T. (2012) A Practical and General Diels–Alder Reaction of Pentafulvenes with Arynes Organic Letters, 14 (16). pp. 4098-4101. ISSN 1523-7060
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Official URL: http://doi.org/10.1021/ol301742k
Related URL: http://dx.doi.org/10.1021/ol301742k
Abstract
A high-yielding, versatile and practical Diels-Alder reaction of pentafulvenes with arynes under mild reaction conditions is reported. The aryne generated by the fluoride induced 1,2-elimination of 2-(trimethylsilyl)aryl triflates undergoes efficient cycloaddition with 6-substituted and 6,6-disubstituted pentafulvenes leading to the formation of benzonorbornadiene derivatives.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society |
| ID Code: | 128705 |
| Deposited On: | 03 Nov 2022 06:54 |
| Last Modified: | 03 Nov 2022 06:54 |
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