Recent advances in N-heterocyclic carbene (NHC)-catalysed benzoin reactions

Menon, Rajeev S ; Biju, Akkattu T ; Nair, Vijay (2016) Recent advances in N-heterocyclic carbene (NHC)-catalysed benzoin reactions Beilstein Journal of Organic Chemistry, 12 . pp. 444-461. ISSN 1860-5397

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Official URL: http://doi.org/10.3762/bjoc.12.47

Related URL: http://dx.doi.org/10.3762/bjoc.12.47

Abstract

N-Heterocyclic carbenes (NHCs) have emerged as a powerful class of organocatalysts that mediate a variety of organic transformations. The Benzoin reaction constitutes one of the earliest known carbon–carbon bond-forming reactions catalysed by NHCs. The rapid growth of NHC catalysis in general has resulted in the development of a variety of benzoin and benzoin-type reactions. An overview of such NHC-catalysed benzoin reactions is presented.

Item Type:Article
Source:Copyright of this article belongs to Beilstein-Institut
Keywords:acyloin reaction; benzoin reaction; N-heterocyclic carbenes; organocatalysis; umpolung
ID Code:128662
Deposited On:03 Nov 2022 06:52
Last Modified:03 Nov 2022 06:52

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