Three-Component Aminoselenation of Arynes

Gaykar, Rahul N. ; Guin, Avishek ; Bhattacharjee, Subrata ; Biju, Akkattu T. (2019) Three-Component Aminoselenation of Arynes Organic Letters, 21 (23). pp. 9613-9617. ISSN 1523-7060

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Official URL: http://doi.org/10.1021/acs.orglett.9b03789

Related URL: http://dx.doi.org/10.1021/acs.orglett.9b03789

Abstract

The three-component coupling of tertiary amines, arynes, and aryl selenium bromide or diaryl diselenide as an electrophilic selenium source allowing the synthesis of 2-selanyl aniline derivatives is reported. This aminoselenation reaction of arynes installs a C-N and C-Se bond under mild conditions, and the products are formed in moderate to good yields. This reaction is compatible with various functional groups, and the preliminary studies on the mechanism of the reaction is also provided.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society
ID Code:128602
Deposited On:03 Nov 2022 06:45
Last Modified:03 Nov 2022 06:45

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