Electron Hopping among Cofacially Stacked Perylenediimides Assembled by Using DNA Hairpins

Wilson, Thea M. ; Zeidan, Tarek A. ; Hariharan, Mahesh ; Lewis, Frederick D. ; Wasielewski, Michael R. (2010) Electron Hopping among Cofacially Stacked Perylenediimides Assembled by Using DNA Hairpins Angewandte Chemie International Edition, 49 (13). pp. 2385-2388. ISSN 1433-7851

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Official URL: http://doi.org/10.1002/anie.200907339

Related URL: http://dx.doi.org/10.1002/anie.200907339

Abstract

Charge on through: Perylenediimide chromophores incorporated into DNA hairpins serve as base-pair surrogates and form a zipperlike intercalated structure (see picture). Electron hopping was observed within the chromophore stacks upon one-electron reduction.

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ID Code:126760
Deposited On:17 Oct 2022 05:33
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