Rearrangement of 1,4,5,6-tetrahalo-7,7-dimethoxybicyclo[2.2.1]hept-5-en-2-ones to phenolic derivatives

Khan, Faiz Ahmed ; Dash, Jyotirmayee ; Jain, Dheeraj ; Prabhudas, B. (2001) Rearrangement of 1,4,5,6-tetrahalo-7,7-dimethoxybicyclo[2.2.1]hept-5-en-2-ones to phenolic derivatives Journal of the Chemical Society, Perkin Transactions 1 (23). pp. 3132-3134. ISSN 1472-7781

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Official URL: http://doi.org/10.1039/B108152G

Related URL: http://dx.doi.org/10.1039/B108152G

Abstract

A simple Diels–Alder route leading to methyl 2,3,4-trihalo-5-hydroxybenzoates via thermal Grob-type rearrangement of easily accessible 1,4,5,6-tetrahalo-7,7-dimethoxybicyclo[2.2.1]hept-5-en-2-one with concomitant methyl halide elimination is described.

Item Type:Article
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