Organic additive-mediated synthesis of novel cobalt(II) hydroxides

Ismail, J. ; Ahmed, M. F. ; Vishnu Kamath, P. ; Subbanna, G. N. ; Uma, S. ; Gopalakrishnan, J. (1995) Organic additive-mediated synthesis of novel cobalt(II) hydroxides Journal of Solid State Chemistry, 114 (2). pp. 550-555. ISSN 0022-4596

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00224...

Related URL: http://dx.doi.org/10.1006/jssc.1995.1084

Abstract

Electrochemical precipitation of cobalt(II) hydroxide from nitrate solutions containing organic molecules, such as glucose, fructose, lactose, glycerol, and citric acid, yields a new modification of cobalt(II) hydroxide (a = 3.09 ± 0.03 Å, c = 23.34 ± 0.36 Å) that is isostructural with α-nickel hydroxide; precipitation in the absence of organic additives gives the stable, brucite-like, βCo(OH)2.

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