Facile base-free in situ generation and palladation of mesoionic and normal N-heterocyclic carbenes at ambient conditions

Sureshbabu, Bemineni ; Ramkumar, Venkatachalam ; Sankararaman, Sethuraman (2014) Facile base-free in situ generation and palladation of mesoionic and normal N-heterocyclic carbenes at ambient conditions Dalton Transactions, 43 (28). pp. 10710-10712. ISSN 1477-9226

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Official URL: http://doi.org/10.1039/c4dt01112k

Related URL: http://dx.doi.org/10.1039/c4dt01112k

Abstract

Synthesis of normal and mesoionic N-heterocyclic carbene Pd(II) complexes in near quantitative yields from the corresponding NHC precursor salts under base free and ambient conditions is reported. A plausible mechanism involving charge-assisted hydrogen bonded intermediates is proposed.

Item Type:Article
Source:Copyright of this article belongs to The Royal Society of Chemistry.
ID Code:124319
Deposited On:12 Nov 2021 12:27
Last Modified:12 Nov 2021 12:27

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